Exp2

Expt 116 Soap From Nutmeg Adapted by Keith Reber (PSU 04) from a mathematical operation given by Marcio de Mattos and David Nicodem (J. Chem. Ed. 2002, 79, 94-95) Revised By Timothy Nowak (PSU 07) entry: For thousands of years, people have produced soap from planks through with(predicate) a carry through known as saponification. Fats and veg oils atomic number 18 generally triesters consisting of three vernacular fat person virulent chains bonded to a corpuscle of glycerol to appoint a triglyceride. When a strong travelling bag much(prenominal) as sodium hydroxide is added to a fat or oil and heated, the ester bonds of the triglycerides are hydrolyzed, and fatty acid salts are produced: O H3 H27CC 13 O O O O O CH3H C 13 27 O NaOH C CH3H27 13 Trimyristin (a fat) 723.14 g/mol mp 56-57°C OH 3 H3 H27CC 13 - O Na OH + EtOH, H2O Reflux 15 min. HO + Sodium myristate (a soap) 228.36 g/mol mp 58°C Glycerol These fatty acid salts have a opposite shoemakers last and a nonpolar end, giving the soap its unusual emulsifying properties. The long hydrocarbon tail is nonpolar and hydrophobic, and therefore splits well in nonpolar environments, such as grease.

The charged head of individually fatty acid salt is polar and water-soluble (hydrophilic): Micelle organize from fat in water (ex: washing grease from workforce with soap) Since the soap is somewhat compatible in both fat and water, it effectively produces emulsions. This is accomplished by the formation of a micelle in which th e fatty acid salts on the whole surround a ! droplet of oil, oriented so that the nonpolar hydrocarbon chains are dissolve in the fat and the polar carboxylate groups are fade away in water. The micelle can then be easily dust away with water, carrying the grease with it. In this experiment, the fat trimyristin bequeath be extracted from ground nutmeg and saponified to produce sodium myristate, a carboxylate salt that functions as a soap. The properties of this soap will be determined through a series...If you want to own a full essay, order it on our website: BestEssayCheap.com

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